One the many challenges facing the countries in the Asia-Pacific today are preparing their societies and governments for globalization and the information and communication revolution. Policy-makers, business executives, NGO activists, academics, and ordinary citizens are increasingly concerned with the need to make their societies competitive in the emergent information economy. This paper presents the how E- commerce is a part of E-Business and importance of E-commerce in today’s globalizationworld and also presents E-payment analysis for reliance product. We evaluate accuracy of transactions and business growth percentages. We used three different types of data sets Bag of Words, Twenty News group data sets, and Legal Case Reports datasets in analyzing of reliance products. India is showing tremendous growth in e-commerce mainly due to low cost of the personal computer and the growing use of mobile and the Internet.